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    • 专利摘要:
    The present invention relates to a transparent ophthalmic lens comprising a substrate having a front main face and a rear main face, said front main face being coated with a multilayer interference coating, preferably anti-reflective, comprising a stack of at least one layer having a refractive index greater than 1.6 and at least one layer having a refractive index less than 1.55, characterized in that: ○ the average reflection factor on said front main face coated with said interference coating, between 350 nm and a wavelength between 380 and 400 nm, preferably between 350 and 380 nm, weighted by the function W (λ), is greater than or equal to 35% for at least one angle of incidence between 0 ° and 17 °. °; The luminous reflection factor at 400 nm on said front main face coated with said interference coating is less than or equal to 35% for at least one angle of incidence between 0 ° and 17 °.
    公开号:FR3031195A1
    申请号:FR1463344
    申请日:2014-12-24
    公开日:2016-07-01
    发明作者:Delphine Passard；Nicolas Maitre
    申请人:Essilor International Compagnie Generale dOptique SA；
    IPC主号:
    专利说明:

    [0001] TECHNICAL FIELD OF THE INVENTION The present invention relates generally to an article, in particular a transparent optical article, such as an ophthalmic lens, comprising an interference stack for reducing the transmission of ultraviolet light through an ophthalmic lens. . State of the art The solar spectrum is composed of electromagnetic radiations of different wavelengths, in particular ultraviolet (UV) radiation. The UV spectrum comprises several bands, in particular the UVA, UVB and UVC bands. Among the UV bands reaching the earth's surface, the UVA band, between 315 nm and 380, and the UVB band, between 280 nm and 315 nm, are particularly harmful for the eye. They are particularly responsible for an acceleration of the ocular aging likely to generate an early cataract or more extreme phenomena like the photokeratitis or "blindness of the snows". It is considered that the UV protection is not adequate when the ophthalmic lens passes more than 1% of the wavelength from 280 to 380 nm. However, certain materials usually used as an ophthalmic lens substrate, for example those obtained by (co) polymerization of diethylene glycol bis allyl carbonate sold, for example, under the trade name CR-39® by PPG Industries (ORMA® lenses). ESSILOR), let some of the ultraviolet rays pass from 350 nm to 380 nm. It has indeed been found that this substrate allowed some of the UV to pass through this wavelength range. Therefore, these materials do not provide perfect protection against harmful ultraviolet light ranging from 280 to 380 nm. This has the consequence of causing two major problems, namely first of all a low value of the sun protection factor of ophthalmic lenses "ESPF" (of the English "Eye-Sun Protection Factor", as defined in the application European Patent EP2607884) of the order of 10/15, then an increase in the yellowing of the substrate due to its degradation by UV over time.
    [0002] Conventional antireflection coatings are designed and optimized to reduce reflection on the glass surface in the visible range, typically in the spectral range of 380 to 780 nm. In general, reflection in the UV domain (280-380 nm) is not optimized. To prevent eye damage caused by these UV rays and to obtain a UV-cut lens (the longest wavelength for which the lens cuts at least 99% of the UV light) greater than or equal to 365 nm, generally equal to at 380 nm, different solutions have been proposed in the prior art. A first solution consists of reducing the reflection in the UV spectrum by coating the rear face of a lens substrate with a multilayer antireflection coating.
    [0003] Document FR 2968774 describes, for example, a lens substrate comprising on its rear face a multilayer antireflection coating. This multilayer antireflection coating has a mean reflection factor Ruv between 280 and 380 nm weighted by the function W (X) defined according to ISO 13666: 1998, less than 5%, for an angle of incidence of 30 ° and 5 for an angle of incidence of 45 °. For example, Example 1 of this document discloses the use of an antireflection coating comprising, starting from the substrate, a stack of 4 layers of high (ZrO2) to low (SI02) refractive index. The UV reflection factor of this example at an angle of incidence of 35 ° is: Ru7 (%) = 4%. The coating tested according to this example also makes it possible to obtain an ESPF sun protection factor ranging from 11 to 25 depending on the substrate tested, as shown in Table 1 below: Orma® 15 Orma® Thin PC MR7® MR8 Substrate ® el, (%) 3.87% 5.26% 0 0 0 ESPF - value 13 11 25 25 25 and class Class 10 Class 10 Class 25 Class 25 Class 25 Table 1: ESPF value of the stack of Example 1 of in use This table thus shows that the ESPF values are lower on the diethylene glycol bis-allyl carbonate-based Orma® lenses than on the other substrates, which confirms that the Orma® substrates transmit UV between 350 nm and 380 nm. . The ESPF value is even lower for the Orma thin® substrate, which has a lower center thickness and therefore allows more harmful UV rays to pass through. Consequently, depending on the substrates, the ophthalmic lens described in document FR 2968774 does not have a sufficient sun protection factor.
    [0004] Another solution for obtaining an ophthalmic lens that cuts UV is to reduce UV transmission ((%)) by, for example, incorporating UV absorbers into ophthalmic lenses. The UV absorber may be incorporated in the mass of the lens, during the polymerization of the monomers forming the lens material, or at the surface thereof, by immersion of the lens (or imbibition) in a bath containing the lens. UV absorber. The incorporation of a UV absorber into the lens is generally accompanied by undesirable yellowing thereof, which can be overcome by combining the UV absorber with a specific dye. EP 1 085 348 discloses a method of incorporating a UV absorber into a lens without causing yellowing thereof. The method comprises mixing a benzotriazole UV absorber with an episulfide or diethylene glycol bis (allyl carbonate) monomer which is then polymerized to form the lens material. The use of this specific UV absorber in this particular process allows long UV absorption.
    [0005] Further, it has been suggested in JP01-230003, a method of imbibing a lens with another benzotriazole derivative, 2- (2-hydroxy-5-methylphenyl) benzotriazole. . However, these solutions using UV absorbers, although satisfactory, employ a rather complex process. Another solution known in the state of the art for reducing the transmission (%) consists in coating the substrate with an antireflection antireflection stack of ultraviolet rays. Document US Pat. No. 5,332,618 describes, for example, a UV-rejection multilayer antireflection coating that can be placed on a transparent subtrate (mineral glass). The coating 10 comprises at least eight layers. It consists alternately from the substrate, of a layer of high refractive index (refractive index greater than or equal to 2.10 for a wavelength of 520 nm) and of a low refractive index layer ( refractive index of less than 1.50 for a wavelength of 520 nm). In particular, a set of five successive layers have a thickness of 1/4 wavelength each, this assembly is surrounded by the two low refractive index layers each having a thickness of 1/8 wavelength at a wavelength of 330 nm. It is indicated that the UV reflection is improved by the thickness constraints of these two low refractive index layers. Example 3 of this document illustrates a coating comprising an alternation of eight layers of high refractive index TiO2 and low refractive index SiO2. The optical article according to this example, which has been reproduced by the Applicant, has a reflection factor at 400 nm of 46% at an angle of incidence of 0 ° and a reflection factor in the UV of 86% for a wavelength range from 350 to 380 nm. Therefore, the coating according to this example has the effect of cutting visible blue light causing undesired yellowing of the optical article. This document also discloses that a layer of high zirconia refractive index (ZrO 2) is not recommended because it would lead to less efficient and / or more complex coatings. Therefore, while these solutions are satisfactory, there is still a need for new optical articles, such as ophthalmic lenses having improved anti-UV properties, while having very good antireflection performance in the visible range and of which The setting is simple. On the other hand, the polycarbonate substrates filter at least 99% of the light at wavelengths below 385 nm, while the poly (thiourethane) substrates filter at least 99% of the light for the lengths of light. lower waves 395-398 nm. In this range of violet visible light from 380 nm to 400 nm, it may also be advantageous to limit transmission through ophthalmic lenses. The present invention thus aims to provide a new optical article, in particular an ophthalmic lens that avoids all or part of the aforementioned drawbacks.
    [0006] In particular, the object of the present invention is to provide a transparent optical article, in particular an ophthalmic lens, comprising a mineral or organic glass substrate comprising on its front face an anti-UV, preferably antireflection, multilayer interference coating. having very good antireflection performance in the visible range, at the same time capable of significantly reducing the transmission of UV radiation, in particular UVA and UVB, compared to a bare substrate or a substrate having a conventional antireflection coating, and whose preparation is industrially easy. SUMMARY OF THE INVENTION The present invention relates to a transparent ophthalmic lens comprising a substrate having a front main face and a rear main face, said front main face being coated with a multilayer interference coating, preferably anti-reflective, comprising a stack at least one layer having a refractive index greater than 1.6, said high refractive index layer, and at least one layer having a refractive index less than 1.55, said layer having a low refractive index, refraction, characterized in that: the average reflection factor on said front main face coated with said interference coating, between 350 nm and a wavelength between 380 and 400 nm, preferably between 350 and 380 nm, weighted by the function W (X), 20 is greater than or equal to 35% for at least one angle of incidence between 0 ° and 17 °, where the light reflection factor at 400 nm on said main face front blade coated with said interference coating is less than or equal to 35% for at least an angle of incidence between 0 ° and 17 °.
    [0007] In the context of the invention, the angle of incidence is conventionally defined as the angle between the normal to the surface at the point of incidence and the direction of the light beam contacting this surface. The present invention also relates to a method of manufacturing an ophthalmic lens as defined above, characterized in that the deposition of the multilayer interference coating 30 is carried out under vacuum. For the remainder of the description, unless otherwise specified, the indication of an interval of values "from X to Y" or between "X and Y" in the present invention means As used herein, when an optical article (or ophthalmic lens) comprises one or more coatings on its surface, the term "deposit a layer or a coating on the article". means that a layer or coating is deposited on the exposed (exposed) surface of the outer coating of the article, i.e., its coating furthest away from the substrate.
    [0008] A coating which is "on" a substrate or which has been "deposited" on a substrate is defined as a coating which (i) is positioned above the substrate, (ii) is not necessarily in contact with the substrate. substrate, i.e. one or more intermediate coatings may be disposed between the substrate and the coating in question, and (iii) does not necessarily cover the substrate completely. In a preferred embodiment, the coating on a substrate or deposited on a substrate is in direct contact with this substrate. When "a layer 1 is located under a layer 2", it will be understood that the layer 2 is further away from the substrate than the layer 1.
    [0009] By the rear (or internal) side of the substrate is meant the face which, when using the optical article (or ophthalmic lens), is closest to the user's eye. This is usually a concave face. Conversely, the front face of the substrate means the face which, when using the optical article (or ophthalmic lens), is furthest from the eye of the user. This is usually a convex face.
    [0010] DESCRIPTION OF THE FIGURES The invention will be described in more detail with reference to the following accompanying drawings, in which: FIG. 1 and FIG. 2 show a graph illustrating the variation of the R percentage reflection (R%) of an article optical (respectively, lens 1 and lens 3) according to the invention prepared respectively according to example 1 and example 3 comprising on its main face before an antireflection coating, at an angle of incidence 0 of 0 °, depending on the wavelength (lambda) in the range of UVA (315 to 380 nm), UVB (280 to 315 nm) and visible (380 to 780 nm), Detailed description of the invention attached to the development of a new ophthalmic lens having a new multilayer interference stack, preferably antireflection having a strong reflection in the field of ultraviolet on the front (convex) measured at an angle of incidence close to normal e. The Applicant has shown that the new multilayer interference stack according to the invention surprisingly makes it possible to reduce the amount of UV passing through the substrates, in particular the Orma® substrates, without, however, reflecting the visible light and without inducing yellowing of the substrate. The lens. The Applicant has also shown that the new multilayer interference stack according to the invention makes it possible to greatly increase the solar protection factor, without increasing the reflection factor in the visible.
    [0011] Finally, the method of producing this new anti-UV multilayer interference stack is easy to implement. In particular, it is easier to implement than the UV absorbers that must be incorporated into the substrate. In addition, it requires the same materials as standard anti-glare coatings.
    [0012] The present invention thus relates to a transparent ophthalmic lens comprising a substrate having a front main face and a rear main face, said front main face being coated with a multilayer interference coating, preferably anti-reflective, comprising a stack of at least one layer having a refractive index greater than 1.6, said high refractive index layer, and at least one layer having a refractive index less than 1.55, said low refractive index layer, characterized in that that: the average reflection factor on said front main face coated with said interference coating, between 350 nm and a wavelength between 380 and 400 nm, preferably between 350 and 380 nm, weighted by the W (X) function, is greater than or equal to 35% for at least an angle of incidence of between 0 ° and 17 °; the luminous reflection factor at 400 nm on said front main face coated with said interference coating is less than or equal to 35% for at least one angle of incidence between 0 ° and 17 °. The present invention proposes indeed an anti-UV multilayer interference coating 20 with the improved design, comprising a stack of thin layers whose thicknesses and materials have been chosen so as to optimize the antireflection performance in the visible range on the one hand and in the UV field on the other hand. This optimization of the antireflection performance has been achieved by taking into account the weighting function W (X) defined in the ISO 13666: 1998 standard, which expresses the distribution of the solar radiation UV weighted by the relative spectral efficiency of this radiation for the wearer. . Over the wavelength range of 280 nm to 380 nm, the average reflection factor corresponds to the Ruv factor well known to those skilled in the art. In order to account for violet visible light in the range of 380 nm to 400 nm, the weighting function W (X) was extrapolated to 400 nm, defining a Ruv analogue extended over ultraviolet and violet lights. The inventors have unexpectedly developed an anti-UV multilayer interference coating having a high reflection in the UV resulting in a decrease in the UV transmission, thus allowing first to increase the value of the ESPF. This second reduction of UV transmitted to the substrate has the second consequence of having a "protective" effect at the level of the latter and consequently of limiting its degradation and therefore its increase of the yellowness index over time. The multilayer interference coatings according to the invention therefore achieve a greater spectral reflection between 280 and 380 nm, without any consequences for the wearer, in order to achieve the best compromise between the antireflection performance in the visible range and the UV range. In general, the multilayer interference coating of the ophthalmic lens according to the invention, which will be called "UV reflective interference coating", may be deposited on any substrate, and preferably on organic glass substrates, for example a substrate. thermoplastic or thermosetting plastic material. Among the thermoplastic materials that are suitable for substrates, mention may be made of (meth) acrylic (co) polymers, in particular poly (methyl methacrylate) (PMMA), thio (meth) acrylic (co) polymers, polyvinyl butyral (PVB) ), polycarbonates (PC), polyesters such as poly (ethylene terephthalate) (PET) or polybutylene terephthalate (PBT), polycarbonate / polyester copolymers, cycloolefin copolymers such as ethylene / norbornene or ethylene / cyclopentadiene copolymers and combinations thereof, ethylene / vinyl acetate thermoplastic copolymers. Among the thermosetting materials which are suitable for substrates, mention may be made of polyurethanes (PU), poly (thiourethanes), polyol allyl carbonates (co) polymers, polyepisulfides and polyepoxides. Other thermosetting materials suitable for substrates are (co) polymers of acrylic type whose refractive index is between 1.5 and 1.65, typically close to 1.6. These acrylic (co) polymers are obtained by polymerization of mixtures of monomers (meth) acrylates and optionally allylic and / or vinyl aromatic monomers. The (meth) acrylate monomers may be monofunctional or multifunctional, typically having from 2 to 6 (meth) acrylate groups. These monomers can be aliphatic, cyclic, aromatic, polyalkoxylated, derivatives of compounds such as bisphenol and / or carrying other functions such as epoxy, thioepoxy, hydroxyl, thiol, sulfide, carbonate, urethane and / or isocyanate. By (co) polymer is meant a copolymer or a polymer. By (meth) acrylate is meant an acrylate or a methacrylate. For the purpose of the present invention, polycarbonate (PC) is intended to mean homopolycarbonates as well as copolycarbonates and copolycarbonates which are sequenced. The substrates may be obtained by polymerizing mixtures of the above monomers, or may further comprise mixtures of these polymers and (co) polymers. Preferably, the substrate according to the invention has a transmission factor T greater than or equal to 1% for a wavelength between 350 nm and 400 nm; The substrates particularly recommended are the substrates obtained by (co) polymerization of diethylene glycol bis allyl carbonate, sold, for example, under the trade name CR-39® by the company PPG Industries (ORMA® ESSILOR lenses), or substrates of acrylic type.
    [0013] In particular, the substrate that is suitable for the invention is the substrate obtained by (co) polymerization of diethylene glycol bis allyl carbonate (CR-390, ORMA® ESS I LOR lenses). Before the deposition of the UV reflective interference coating on the optionally coated substrate 5, for example an anti-abrasion and / or anti-scratch layer or an underlayer, it is common to subject the surface of said substrate, optionally coated, with a physical or chemical activation treatment, intended to increase the adhesion of the UV reflective interference coating. This pre-treatment is generally conducted under vacuum. It can be a bombardment with energetic species, for example an ion beam ("Ion 10 Pre-Cleaning" or "IPC"), a corona discharge treatment, effluvage, a treatment UV, or vacuum plasma treatment, usually an oxygen or argon plasma. It can also be an acidic or basic surface treatment and / or by solvents (water or organic solvent). In the present invention, the "average light reflection factor," denoted Rv, is as defined in ISO 13666: 1998, and measured in accordance with ISO 8980-4 (at an angle of incidence of less than 17%). °, typically cb 15 °, that is to say that it is the weighted average of the spectral reflection over the entire visible spectrum between 380 and 780 nm, preferably the reflection factor in the Rv visible between 380 nm and 780 nm on said front main face coated with said UV reflective interference coating is less than or equal to 3%, preferably less than or equal to 1.5%. 400 nm on said front main face coated with said UV reflective interference coating is less than or equal to 25%, preferably less than or equal to 15% for at least one angle of incidence between 0 ° and 17 °. invention, we define the average reflection factor between 280 and 380 nm weighted by the function W (X) defined in ISO 13666: 1998 and denoted Ruv, by: 380 fW (2) .R (2) .d2 280 Ruy 380 fW (2) .d2 280 where R (X) denotes the spectral reflection factor of the glass at the wavelength 30 considered, and W (X) denotes a weighting function equal to the product of the solar spectral irradiance Es (X) and the function Relative spectral efficiency S (X). By analogy, the average reflection factor weighted by the function W (X) can be defined between two wavelengths X1 and X2 by taking up the equation above and taking as limits the integrals the wavelengths X1 and X2.
    [0014] The spectral function W (X), which makes it possible to calculate the average transmission factors of the UV radiation, is defined in the ISO 13666: 1998 standard. It makes it possible to express the distribution of UV solar radiation moderated by the relative spectral efficiency of this radiation for the wearer, since it takes into account at the same time the spectral energy of the sun Es (X), which globally emits low UVB compared to UVA, and spectral efficiency S (X), UVB being more harmful than UVA. This function has been extrapolated for violet visible light from 385 to 400 nm in the context of the invention. The values of these three functions in the UV domain are indicated in the following table 2 (the shaded areas are extrapolated): Table 2 It should be noted that the weighting function W (X) is zero or almost zero between 280 nm and 295 nm, which means that the weighted average reflection factor is also zero in this wavelength range. This means that even if the level of reflection is high over this spectral range, there will be no consequence on the value of the Ruv average weighted reflection factor calculated between 280 and 380 nm. According to the invention, the UV reflective interference coating deposited on the main front face of the substrate preferably has a mean reflection factor on λ (λ) (nm) (mW / m2.nm) S (λ) W (A) = Es (A) .S (A) 0 0 0 2.09x104 8.10x10-2 3051.91 310 11.0 315 30.0 320 54.0 325 79.2 330 101 335 128 340 151 345 170 350 188 355 210 360 233 365 253 370 279 375 306 380 336 385 390 395 400 0.88 0.77 0.64 0.54 0.30 0.060 0.015 0.003 0.0010 0.00050 0.00041 0.00034 0.00028 0.00024 0.00020 0.00016 0.00013 0.00011 0.000093 0.000077 0.000064 0.00011 0.0243 0.115 0.165 0.09 0.054 0.04 0.044 0.042 0.041 0.038 0.034 0.03 0.028 0.024 0.024 Said main front face between 350 nm and a wavelength between 380 and 400 nm, weighted by the function W (X), greater than or equal to 50%, preferably greater than or equal to 65% for at least one angle of incidence between 0 ° and 17 °. According to one characteristic of the invention, the colorimetric coefficients of the UV reflective interferential coating of the invention in the CIE L * a * b * colorimetric system are calculated between 380 and 780 nm taking into account the D65 illuminant and of the observer 10 °. It is possible to prepare UV reflective interference coatings without limitation as to their hue angle. However, the hue angle h preferably varies from 90 ° to 180 °, preferably from 120 ° to 150 °, which produces a coating having a green reflection, and the chroma C * is generally less than or equal to 15, preferably less than 10 for at least one angle of incidence between 0 ° and 17 °. The UV reflective, preferably antireflection interference coating of the invention comprises a stack of at least one layer of high refractive index and at least one layer of low refractive index. More preferably, it comprises at least two layers of low refractive index (BI) and at least two layers of high refractive index (HI). This is a simple stack, since the total number of layers of the UV reflective interference coating is greater than or equal to 3, preferably greater than or equal to 4. In particular, the UV reflective interference coating of the The invention comprises a number of layers greater than or equal to 3, preferably greater than or equal to 4, ideally greater than or equal to 6 and a number of layers less than or equal to 10, preferably less than or equal to 8. A layer of the coating UV reflective interference is defined as having a thickness greater than or equal to 1 nm. Thus, any layer having a thickness less than 1 nm will not be counted in the number of layers of the UV reflective interference coating. Unless otherwise indicated, all the thicknesses disclosed in this application are physical thicknesses. It is not necessary that the HI and BI layers be alternated in the stack, although they may be alternated according to one embodiment of the invention. Two (or more) HI layers may be deposited one on top of the other, just as two (or more) BI layers may be deposited one on top of the other. In the present application, a layer of the UV reflective interfering coating, preferably antireflection, is said layer of high refractive index (HI) when its refractive index is greater than 1.6, preferably greater than or equal to 1.65 more preferably greater than or equal to 1.7, more preferably greater than or equal to 1.8 and still more preferably greater than or equal to 1.9. A layer of the UV reflective interfering coating, preferably anti-reflective, is called a low refractive index (BI) layer when its refractive index is less than 1.55, preferably less than or equal to 1.48, better still less than or equal to at 1.47.
    [0015] Unless otherwise indicated, the refractive indexes referred to herein are expressed at 25 ° C for a wavelength of 550 nm. The HI layer is a conventional high refractive index layer, well known in the art. It generally comprises one or more inorganic oxides such as, without limitation, zirconia (ZrO 2), titanium oxide (TiO 2), alumina (Al 2 O 3), tantalum pentoxide (Ta 2 O 5), neodymium oxide (Nd205), praseodymium oxide (Pr203), praseodymium titanate (PrTiO3), La203i Nb205i Y203. Optionally, the high index layers may also contain silica or other materials of low refractive index, provided that their refractive index is greater than 1.6 as indicated above. Preferred materials are TiO 2, PrTiO 3, ZrO 2, Ta 2 O 5, Al 2 O 3, Y 2 O 3 and mixtures thereof. Preferably, the layer or layers HI are zirconia (ZrO2). The layer BI is also well known and may comprise, without limitation, silicon oxide, or a mixture of silica and alumina, in particular silica doped with alumina, the latter contributing to increasing the thermal resistance of the UV reflective interfering coating. The layer BI is preferably a layer comprising at least 80% by weight of silica, better still at least 90% by weight of silica, relative to the total mass of the layer, and better still consists of a silica layer. Optionally, the low index layers may also contain materials of high refractive index, provided that the refractive index of the resulting layer is less than 1.55. When a BI layer comprising a mixture of SiO 2 and Al 2 O 3 is used, it preferably comprises from 1 to 10%, better still from 1 to 8% and even more preferably from 1 to 5% by weight of Al 2 O 3 relative to the mass. total of SiO 2 + Al 2 O 3 in this layer. For example, SiO 2 doped with 4% or less Al 2 O 3 by weight, or SiO 2 doped with 8 (3% Al 2 O 3 can be employed.) Commercially available SiO 2 / Al 2 O 3 mixtures can be used, such as LIMA ® marketed by Umicore Materials AG (refractive index n = 1.48-1.50 at 550 nm), or the substance L5® marketed by Merck KGaA (refractive index n = 1.48 at 500 nm). UV-reflective antireflection coating is generally a silica-based layer, preferably comprising at least 80% by weight of silica, more preferably at least 90% by weight of silica (for example a silica layer doped with silica). alumina), with respect to the total mass of the layer, and even better consists of a layer of silica Generally, the HI layers have a physical thickness ranging from 10 to 120 nm, and the BI layers have a physical thickness ranging from 10 to 100 nm.
    [0016] Generally, the total thickness of the UV reflective interference coating is less than 1 micrometer, preferably less than or equal to 800 nm, more preferably less than or equal to 500 nm and more preferably less than or equal to 250 nm. The total thickness of the UV reflective interference coating is generally greater than 100 nm, preferably greater than 150 nm.
    [0017] According to a preferred variant embodiment, the UV reflective interference coating according to the invention does not contain titanium. According to one embodiment of the invention, the UV reflective interferential coating, preferably antireflection is deposited on an underlayer. It is believed that this underlayer is not part of the UV reflective interference coating. By underlayer of the UV reflective interferential coating is meant a coating of relatively large thickness, used for the purpose of improving the mechanical properties such as the resistance to abrasion and / or scratching of said coating and / or or to promote its adhesion to the underlying substrate or coating.
    [0018] In view of its relatively large thickness, the underlayer generally does not participate in the anti-reflective optical activity, in particular in the case where it has a refractive index close to that of the underlying coating (which is generally the anti-abrasion and anti-scratch coating) or that of the substrate, when the underlayer is directly deposited on the substrate. Therefore, the underlayer, when present, is not considered to be part of the UV reflective interference coating. The underlayer must have a thickness sufficient to promote the abrasion resistance of the UV reflective interference coating, but preferably not so great as not to cause light absorption which, depending on the nature of the underlayer, could significantly reduce the relative transmission factor ty. Its thickness is generally less than 300 nm, better 200 nm, and is generally greater than 90 nm, better 100 nm. The underlayer preferably comprises a layer based on SiO 2, this layer preferably comprising at least 80% by weight of silica, better still at least 90% by weight of silica, relative to the total weight of the layer, and even better is a layer of silica. The thickness of this silica-based layer is generally less than 300 nm, more preferably 200 nm, and is generally greater than 90 nm, more preferably 100 nm. According to another embodiment, this layer based on SiO 2 is a silica layer doped with alumina, in proportions as defined above, preferably consists of a silica layer doped with alumina. . According to a particular embodiment, the sublayer consists of a layer of SiO2. It is preferable to use a monolayer sub-layer. However, the underlayer may be laminated (multilayer), particularly when the underlayer and underlying coating (or substrate, if the underlayer is deposited directly on the substrate) exhibit a difference in index significant refraction. The ophthalmic lens of the invention can be made antistatic, that is to say not to retain and / or develop an appreciable electrostatic charge, thanks to the incorporation of at least one electrically conductive layer in the stack present at the surface of the ophthalmic lens. This electrically conductive layer is preferably located between two layers of the interfering UV reflective coating, and / or is adjacent to a high refractive index layer of this UV reflective interference coating. Preferably, the electrically conductive layer is located immediately under a layer of low refractive index of the UV reflective interference coating, ideally constitutes the penultimate layer of the UV reflective interference coating being located immediately below the outer layer of the UV reflective interfering coating. silica base of the UV reflective interference coating. The electrically conductive layer should be thin enough not to alter the transparency of the UV reflective interference coating. The electrically conductive layer is preferably made from an electrically conductive and highly transparent material, generally an optionally doped metal oxide. In this case, its thickness preferably varies from 1 to 15 nm, better from 1 to 10 nm. The electrically conductive layer preferably comprises an optionally doped metal oxide selected from indium, tin, zinc oxides and mixtures thereof. Tin-indium oxide (In203: Sn, indium oxide doped with tin), zinc oxide doped with aluminum (ZnO: Al), indium oxide (In203) and tin oxide (SnO2) are preferred. According to an optimal embodiment, the electrically conductive and optically transparent layer is a layer of tin-indium oxide, denoted ITO layer or a tin oxide layer.
    [0019] Generally, the electrically conductive layer contributes, within the stack, but in a limited way, due to its small thickness, to obtaining anti-reflective properties and constitutes a high refractive index layer in the reflective interference coating. UV. This is the case of layers made from an electrically conductive and highly transparent material such as ITO layers.
    [0020] The various layers of the UV-reflective interference coating and the optional sub-layer are preferably deposited by vacuum deposition according to one of the following techniques: i) by evaporation, possibly assisted by ion beam ii) by beam sputtering ion iii) by cathodic sputtering iv) by plasma enhanced chemical vapor deposition. These different techniques are described in the books "Thin Film Processes" and "Thin Film Processes II," Vossen & Kern, Ed., Academic Press, 1978 and 1991 respectively. A particularly recommended technique is the vacuum evaporation technique.
    [0021] Preferably, the deposition of each of the layers of the UV reflective interference coating and the optional undercoat is carried out by vacuum evaporation. According to one embodiment of the invention, the anti-UV interference coating comprises, in the direction of removal of the substrate optionally coated with one or more functional coatings and with an underlayer of 100 to 200 nm of thickness, preferably silica, a high refractive index layer having a refractive index greater than 1.6 from 15 to 39 nm thick, a low refractive index layer having a refractive index less than 1.55 from 26 to 62nm thick, a high refractive index layer having a refractive index greater than 1.6 from 24 to 63nm thick, a low refractive index layer having a refractive index lower than 1.55 from 52 to 81 nm thick, a high refractive index layer having a refractive index greater than 1.6 from 24 to 45 nm thick, a low refractive index layer having a refractive index less than 1.55 from 27 to 64nm thickness, a high refractive index layer having a refractive index greater than 1.6 from 28 to 58 nm thick, optionally an electrically conductive layer 3 to 10 nm thick, and a low refractive index layer having a refractive index of less than 1.55 from 84 to 116 nm in thickness.
    [0022] According to another embodiment, the UV reflective interferential coating comprises, in the direction of removal of the substrate, possibly coated with one or more functional coatings and with a sub-layer of 100 to 200 nm. thickness, preferably silica, a high refractive index layer having a refractive index greater than 1.6 of 15 to 35 nm thick, a low refractive index layer having a refractive index less than 1, From 42 to 62 nm thick, a high refractive index layer having a refractive index greater than 1.6 from 24 to 44 nm thick, a low refractive index layer having a refractive index less than 1 , 55 from 61 to 81 nm thick, a high refractive index layer having a refractive index greater than 1.6 from 25 to 45nm thick, a low refractive index layer having a refractive index lower than 1,55 from 35 to 57nm of shoulder a high refractive index layer having a refractive index greater than 1.6 from 30 to 58 nm in thickness, optionally an electrically conductive layer of 3 to 1 μm in thickness, and a layer of low refractive index; refraction having a refractive index less than 1.55 of 84 to 114 nm thick. According to another embodiment, the UV reflective interference coating comprises, in the direction of the distance from the substrate, optionally coated with one or more functional coatings and with a sub-layer of 100 to 200 nm in diameter. thickness, preferably silica, a high refractive index layer having a refractive index greater than 1.6 from 19 to 39 nm thick, a low refractive index layer having a refractive index less than 1.55 from 26 to 46 nm thick, a high refractive index layer having a refractive index greater than 1.6 from 43 to 63 nm thick, a low refractive index layer having a refractive index of less than 1, From 52 to 72 nm thick, a high refractive index layer having a refractive index greater than 1.6 24 to 44 nm thick, a low refractive index layer having a refractive index less than 1 , 55 from 44 to 64nm thick r, a high refractive index layer having a refractive index greater than 1.6 of 28 to 48 nm thick, optionally an electrically conductive layer 3 to 10 nm thick, and a low refractive index layer having a refractive index of less than 1.55 from 95 to 116 nm in thickness. According to a preferred embodiment of the invention, the rear face of the ophthalmic lens of the invention is also coated with a conventional antireflection coating, different from that on its front face to limit the reflection of UV coming from sides and / or back of the lens. Thus, according to a preferred embodiment, the rear face of the ophthalmic lens is coated with an antireflection coating such that the reflection factor in the UV R ,, on said rear main face between 280 nm and 380 nm weighted by the function W (X) is less than or equal to 10%, preferably less than or equal to 5%, ideally less than or equal to 3%, for an angle of incidence of 35 °. In the context of the invention, the ESPF value of an ophthalmic lens is given by the following relationship: ESPF = ,, o Tt; v (%) + RUS (%) 100% where 3031195 16 Tu ° (% ) is the amount of UV (between 280 and 380 nm) transmitted at an angle of incidence of 0 ° (ie the UV source is perpendicular to the glass), RUS (% o) is the amount of UV (between 280 nm and 380nm) reflected at an angle of incidence of 35 ° on the rear face.
    [0023] The values of ESPF calculated according to the formula below are illustrated in the following table, for Ruv values on the rear face of less than 5%, for different Ruv values on the front face and for the ORMA® material: ESPF 1- Ruv - 0 ° front face on ORMA® Ruv @ 35 ° rear 1 0.65 0.5 0.35 0.2 0 0.05 11.27 13.31 14.42 15.74 17.32 20.00 0 , 04 12.71 15.35 16.85 18.68 20.95 25.00 0.03 14.56 18.13 20.26 22.96 26.50 33.33 0.02 17.04 22.15 25.41 29.81 36.05 50.00 0.01 20.53 28.45 34.07 42.47 56.37 100.00 Table 3 10 The light gray boxes correspond to an ESPF of 15 to 20 and the dark gray boxes with an ESPF greater than 20. Thus, the ophthalmic lens comprising the UV reflective interference coating according to the invention and an antireflection coating for UV (as mentioned above) on the rear face has an excellent index of ESPF sun protection.
    [0024] Preferably, the ESPF coefficient of the ophthalmic lens according to the invention is greater than 10, preferably greater than 15, ideally greater than 20. However, it is possible to apply a UV reflective UV reflective interference coating such as described in the present application on the rear face of the ophthalmic lens. The UV reflective multilayer interference coatings of the front face and the rear face may then be identical or different. According to one embodiment of the invention, the ophthalmic lens rear face is not coated with a multilayer interference reflective UV coating according to the invention. The UV reflective interference coating can be deposited directly on a bare substrate.
    [0025] In some applications, it is preferable that the main face of the substrate is coated with one or more functional coatings prior to deposition of the UV reflective interference coating of the invention. These functional coatings conventionally used in optics may be, without limitation, a shock-proof primer layer, an anti-abrasion and / or anti-scratch coating, a polarized coating, a photochromic coating or a colored coating. Preferably, the ophthalmic lens does not comprise a photochromic coating and / or does not comprise a photochromic substrate.
    [0026] Generally, the main front face of the substrate on which a UV reflective interference coating is deposited is coated with a layer of shockproof primer, an anti-abrasion and / or anti-scratch coating, or a layer. shock-proof primer coated with an abrasion-resistant and / or anti-scratch coating.
    [0027] The UV reflective interfering coating of the invention is preferably deposited on an anti-abrasion and / or anti-scratch coating. The anti-abrasion and / or anti-scratch coating may be any layer conventionally used as an anti-abrasion and / or anti-scratch coating in the field of ophthalmic lenses. The abrasion-resistant and / or scratch-resistant coatings are preferably hard coatings based on poly (meth) acrylates or silanes, generally comprising one or more mineral fillers for increasing the hardness and / or the refraction of the coating once cured. The abrasion-resistant and / or anti-scratch hard coatings are preferably made from compositions comprising at least one alkoxysilane and / or a hydrolyzate thereof, obtained for example by hydrolysis with a hydrochloric acid solution and optionally condensation and / or curing catalysts. Among the coatings recommended in the present invention, mention may be made of epoxysilane hydrolysate-based coatings such as those described in patents FR 2702486 (EP 0614957), US 4,211,823 and US 5,015,523.
    [0028] A preferred anti-abrasion and / or anti-scratch coating composition is that disclosed in FR 2702486, in the name of the applicant. It comprises an epoxy trialkoxysilane and dialkyl dialkoxysilane epoxy hydrolyzate, colloidal silica and a catalytic amount of aluminum curing catalyst such as aluminum acetylacetonate, the remainder consisting essentially of conventionally used solvents. for the formulation of such compositions. Preferentially, the hydrolyzate used is a hydrolyzate of γ-glycidoxypropyltrimethoxysilane (GLYMO) and dimethyldiethoxysilane (DMDES). The anti-abrasion and / or anti-scratch coating composition may be deposited on the main surface of the substrate by dipping or centrifugation. It is then cured by the appropriate route (preferably thermal, or UV). The thickness of the anti-abrasion and / or anti-scratch coating generally varies from 2 to 10 μm, preferably from 3 to 5 μm. Prior to depositing the anti-abrasion and / or anti-scratch coating, it is possible to deposit on the substrate a primer coating improving the impact resistance and / or adhesion of the subsequent layers in the final product. This coating may be any layer of shockproof primer conventionally used for articles made of transparent polymeric material, such as ophthalmic lenses. Among the preferred primer compositions, mention may be made of compositions based on thermoplastic polyurethanes, such as those described in Japanese patents JP 63-3031195 18 141001 and JP 63-87223, the poly (meth) acrylic primer compositions, such as those described in US Pat. No. 5,015,523, compositions based on thermosetting polyurethanes, such as those described in patent EP 0404111 and compositions based on poly (meth) acrylic or polyurethane type latex, such as those described in US Pat. U.S. Patent Nos. 5,316,791 and EP 0680492. Preferred primer compositions are polyurethane-based compositions and latex-based compositions, particularly polyurethane latices optionally containing polyester units. Among the commercial primer compositions suitable for the invention, there may be mentioned Witcobond (R) 232, Witcobond (R) 234, Witcobond (R) 240, Witcobond (R) 242, Neorez (R) R-962, Neorez (R) R-972, Neorez (R) R-986 and Neorez (R) R-9603. Mixtures of these latices, in particular polyurethane latex and poly (meth) acrylic latex, can also be used in the primer compositions. These primer compositions can be deposited on the faces of the article by dipping or centrifugation and then dried at a temperature of at least 70 ° C. and up to 100 ° C., preferably of the order of 90 ° C. C, extending from 2 minutes to 2 hours, generally of the order of 15 minutes, to form primer layers having thicknesses, after firing, of 0.2 to 2.5 μm, preferably 0.5 at 1.5 lm. The ophthalmic lens according to the invention may also comprise coatings formed on the UV reflective interference coating and capable of modifying its surface properties, such as hydrophobic and / or oleophobic coatings (anti-fouling top coat). These coatings are preferably deposited on the outer layer of the UV reflective interference coating. Their thickness is generally less than or equal to 10 nm, preferably from 1 to 10 nm, more preferably from 1 to 5 nm.
    [0029] These are generally fluorosilane or fluorosilazane type coatings. They can be obtained by depositing a fluorosilane or fluorosilazane precursor, preferably comprising at least two hydrolyzable groups per molecule. The precursor fluorosilanes preferentially contain fluoropolyether groups and better still perfluoropolyether groups. These fluorosilanes are well known and are described, inter alia, in US Patents 5,081,192, US 5,763,061, US 6,183,872, US 5,739,639, US 5,922,787, US 6,337,235, US 6,277,485 and EP 0933377. A hydrophobic coating composition and The preferred oleophobe is marketed by Shin-Etsu Chemical under the name KP 801 M (R). Another preferred hydrophobic and / or oleophobic coating composition is commercially available from Daikin Industries under the name OPTOOL DSX (R). It is a fluorinated resin comprising perfluoropropylene groups. Typically, an ophthalmic lens according to the invention comprises a substrate successively coated on its front face with a layer of shockproof primer, with an anti-abrasion and / or anti-scratch layer, with a multilayer interference-free anti-UV coating according to the invention. invention, and a hydrophobic and / or oleophobic coating. The ophthalmic lens according to the invention is preferably an ophthalmic lens for spectacles (spectacle lens), or an ophthalmic lens blank. The lens may be a polarized lens, a photochromic lens or a sun lens, tinted, with or without correction.
    [0030] The rear face of the ophthalmic lens substrate may be sequentially coated with a layer of shockproof primer, an abrasion-resistant and / or anti-scratch layer, an antireflection coating which may or may not be an interference coating. multilayer anti-UV according to the invention, and a hydrophobic coating and / or oleophobic. According to one embodiment, the ophthalmic lens according to the invention does not absorb in the visible or absorbs little in the visible, which means, within the meaning of the present application, that its transmission factor in the visible iv, still Relative relative transmission factor in the visible, is greater than 90%, better than 95%, better still greater than 96 (3/0 and optimally greater than 97'Vo. The factor iv meets a standardized international definition ( ISO 13666: 1998) and is measured in accordance with ISO 8980-3 and is defined in the wavelength range of 380 to 780 nm Preferably, the light absorption of the ophthalmic lens coated according to In addition, the ophthalmic lens according to the invention advantageously enters into the embodiment of a pair of spectacles, Thus, the invention also proposes a pair of spectacles 20 comprising at least one ophthalmic lens. Finally, the present invention relates to a method of manufacturing an ophthalmic lens as described above, characterized in that the deposition of the UV reflective interference coating is carried out under vacuum. In particular, the UV reflective interferential coating is deposited under vacuum according to one of the following techniques: i) by evaporation, possibly assisted by ion beam ii) by ion beam sputtering iii) by cathodic sputtering iv) by plasma enhanced chemical vapor deposition.
    [0031] These various techniques are described in the books "Thin Film Processes" and "Thin Film Processes II," Vossen & Kern, Ed., Academic Press, 1978 and 1991 respectively. A particularly recommended technique is the vacuum evaporation technique.
    [0032] Examples 1. General Procedures The ophthalmic lenses employed in the examples include an ORMA® ESSILOR lens substrate having a diameter of 65 mm, a refractive index of 1.50, a power of 2.00 diopters and a thickness of 1 mm. , 2 mm, coated on its rear face with the anti-abrasion and anti-scratch coating (hard coat) disclosed in example 3 of patent EP 0614957 (refractive index equal to 1.47 and thickness 3.5 1m), based on a hydrolyzate of GLYMO and DMDES, colloidal silica and aluminum acetylacetonate, and then an antireflective multilayer interference coating according to the invention. Said anti-abrasion and anti-scratch coating was obtained by deposition and curing of a composition comprising, by mass, 224 parts of GLYMO, 80.5 parts of 0.1 N HCl, 120 parts of DMDES, 718 parts of colloidal silica. 30% by weight in methanol, 15 parts of aluminum acetylacetonate and 44 parts of ethylcellosolve. The composition also comprises 0.1% of surfactant FLUORADTM FC-430 (R) of 3M by weight relative to the total mass of the composition. The layers of the antireflection coating were deposited without heating the substrates by evaporation under vacuum (evaporation source: electron gun).
    [0033] The deposition frame is a Satis 1200DLF machine equipped with a Temescal electron gun (8kV) for the evaporation of the oxides, and an ion gun (Veeco Mark II) for the preliminary phase of preparation of the surface of the substrate by argon ions (IPC). The thickness of the layers is controlled by means of a quartz microbalance. Spectral measurements were performed on a Perkin-Elmer Lambda 850 variable incidence spectrophotometer with a Universal Reflectance Accessory (URA). 2. Procedure The process for preparing ophthalmic lenses comprises introducing the coated substrate onto its front face of the anti-abrasion and anti-scratch coating in a vacuum deposition chamber, a pumping step until it is obtained. a secondary vacuum, a step of activating the substrate surface with an argon ion beam, stopping the ion irradiation, forming on the anti-abrasion and anti-scratch coating of the underlayer then different layers of the antireflection coating by successive evaporation and finally a ventilation step. 3. Tested Compositions The structural characteristics and optical performance of the ophthalmic lenses 1 to 3 obtained according to Examples 1 to 3 are detailed below. The underlay appears grayed out. The thin ITO layer provides an antistatic property to the glass. Its optical index is 3031195 21 close to Zr02. It is therefore considered that the ITO layer and the ZrO 2 layer form a layer of high refractive index. The values of the average factors of reflection in the UV and in the visible are those of the front face and are indicated for an angle of incidence of 0 ° (measurements made according to the IS08980-4 standard). Lens 1 Lens 2 Lens 3 Index Example 1 Example 2 Example 3 Refraction (thickness (thickness (physical thickness) physical) Air 1 SiO 2 1.47256 94 nm 105 nm 106 nm ITO 2.0592 6.5 nm 6.5 nm 6.5 nm ZrO 2 1.997 48 nm 38 nm 38 nm SiO 2 1.47256 37 nm 54 nm 51 nm ZrO 2 1.997 35 nm 34 nm 35 nm SiO 2 1.47256 71 nm 62 nm 69 nm ZrO 2 1,997 34 nm 53 nm 37 nm SiO 2 1.47256 52 nm 36 nm 53 nm ZrO 2 1.997 25 nm 29 nm 19 nm SiO 2 underlayer 1.4636 150 nm 150 nm 150.0 nm Substrate 2 mm Performance C * 9 9 9 h 145 135 135 Rv 0.70% 0 , 88% 0.85% average factor 65.4% 67.7% 69.5% reflection [280 nm-380 nm] average factor of 43% 62% 57% reflection [350 nm-380 nm] factor means of 35% 53% 48% reflection [350 nm-400 nm] Tuv * [280 nm-380 nm] 1.34% 1.25% 1.18% * Tuv = Tuv (Orma nu) (1-Ruv) = 3 87% (1-Ruv) Table 4 3031195 22 The reflection graphs between 280 and 780 nm of some of the prepared articles (lens 1 and lens 3) are shown in FIGS. 1 and 2 for one year. angle of incidence of 0 °. 4. Result 5 It can be observed that ophthalmic lenses 1 to 3 have very good antireflection properties in the visible range (Rv <0.88%), while reducing the transmission in the UV (Tuv <1.34%) and having an excellent mean reflection factor in the UV: greater than 65% over the range [280 nm-380 nm]) and in particular greater than 57% in the range from 350 nm to 380 nm which is the most problematic for the Orma® substrate.
    [0034] The lenses obtained according to Examples 1 to 3 also have excellent transparency properties, good resistance to abrasion and scratching, and good resistance to hot water quenching followed by solicitation. surface mechanics. The adhesion of the coatings to the substrate is also very satisfactory. 5. Comparative tests Reflectance at 400nm Rv factor factor factor reflection [350nm400nm] reflection means [280nm-380nm] reflection means [350nm-380nm] Ex 3 of 46.4% 0.40% 57% 86% 81% US5332618 Example 1 2.3% 0.70% 65.4% 43% 35% Example 2 14.5% 0.88% 67.7% 62% 53% Example 3 12.5% 0.85% 69.5% 57% 48% Table 5 As can be seen, ophthalmic lenses according to the invention allow to obtain an important reflection of the UV rays (here, in normal incidence), in particular for the problematic range of 350 to 380 nm (lenses 2 and 3), while presenting a weak light reflection at 400 nm. 6. ESPF values of the lens The lenses obtained according to Examples 1 to 3 can be coated on the backside with an antireflection coating of Ruv between 280 and 380 nm of less than 5% at an angle of incidence of 35 °. With the coating of example 1 of patent FR2968774, the ESPF values are greater than 20 (Table 6): 3031195 23 Tuve0 ° on ORMA Ruv @ 35 ° back side ESPF (Tuv = 3.87% (1- Ruv )) Example 1 1.34% 3% 23 Example 2 1.25% 3% 23.5 Example 3 1.18% 3% 24 Table 6 Although the invention has been described in connection with several particular embodiments, it is obvious that It is in no way limited and includes all the technical equivalents of the means described and their combinations if they fall within the scope of the invention.
    权利要求:
    Claims (15)
    [0001]
    REVENDICATIONS1. A transparent ophthalmic lens comprising a substrate having a front main face and a rear main face, said front main face being coated with a multilayer interference coating, preferably anti-reflective, comprising a stack of at least one layer having a refractive index greater than 1.6, said high refractive index layer, and at least one layer having a refractive index of less than 1.55, said low refractive index layer, characterized in that: o the average factor of reflection on said front main face coated with said interferential coating, between 350 nm and a wavelength between 380 and 400 nm, preferably between 350 and 380 nm, weighted by the W (1) function, is greater than or equal to 35% for minus an angle of incidence between 0 ° and 17 °; the luminous reflection factor at 400 nm on said front main face coated with said interference coating is less than or equal to 35% for at least one angle of incidence between 0 ° and 17 °.
    [0002]
    Ophthalmic lens according to claim 1, wherein said average reflection factor on said front main face between 350 nm and a wavelength between 380 and 400 nm is greater than or equal to 50%, preferably greater than or equal to 65%. for at least one angle of incidence between 0 ° and 17 °.
    [0003]
    An ophthalmic lens according to claim 1 or claim 2, wherein the luminous reflectance at 400 nm on said front main face coated with said interferential coating is less than or equal to 25%, preferably less than or equal to 15% for minus an angle of incidence between 0 ° and 17 °.
    [0004]
    An ophthalmic lens according to any one of the preceding claims, wherein said multilayer interference coating comprises a number of layers greater than or equal to 3, preferably greater than or equal to 4, ideally greater than or equal to 6 and a number of layers. less than or equal to 10, preferably less than or equal to 8.
    [0005]
    An ophthalmic lens according to any one of the preceding claims, wherein the one or more high refractive index layers of the multilayer interference coating have a refractive index greater than or equal to 1.8, preferably greater than or equal to 1, 9.
    [0006]
    An ophthalmic lens according to any one of the preceding claims, wherein said multilayer interference coating does not contain titanium.
    [0007]
    An ophthalmic lens according to any one of the preceding claims, wherein the light reflected on said front main face coated with said interferential coating has a chroma C * less than or equal to 15, preferably less than or equal to 10 for at least one incidence angle between 0 ° and 17 °. 3031195
    [0008]
    8. Ophthalmic lens according to any one of the preceding claims, wherein the substrate has a transmission factor T greater than or equal to 1% for a wavelength between 350 nm and 400 nm.
    [0009]
    An ophthalmic lens according to any one of the preceding claims, wherein the visible reflection factor Rv between 380 nm and 780 nm on said front main face coated with said interferential coating is less than or equal to 3%, preferably less than or equal to 3%. or equal to 1.5%.
    [0010]
    Ophthalmic lens according to one of the preceding claims, characterized in that the interferential coating comprises, in the direction away from the substrate, a layer of high refractive index having a refractive index greater than 1.6. from 15 to 39 nm thick, a low refractive index layer having a refractive index less than 1.55 from 26 to 62 nm thick, a high refractive index layer having a refractive index greater than 1 , 6 from 24 to 63nm thick, a low refractive index layer having a refractive index less than 1.55 from 52 to 81nm thick, a high refractive index layer having a refractive index greater than 1 , A layer of low refractive index having a refractive index less than 1.55 from 27 to 64 nm thick, a layer of high refractive index having a refractive index greater than 1.6 from 28 to 58 nm thick, optionally an electrically conductive layer 3 to 10 nm thick, and a low refractive index layer having a refractive index less than 1.55 from 84 to 116 nm thick.
    [0011]
    Ophthalmic lens according to claim 10, characterized in that the interferential coating comprises, in the direction away from the substrate, a layer of high refractive index having a refractive index greater than 1.6 from 15 to 35. nm thick, a low refractive index layer having a refractive index less than 1.55 of 42 to 62nm thick, a high refractive index layer having a refractive index greater than 1.6 from 24 to 44nm thick, a low refractive index layer having a refractive index less than 1.55 from 61 to 81nm thick, a high refractive index layer having a refractive index greater than 1.6 from 25 to 45 nm thick, a low refractive index layer having a refractive index of less than 1.55 27 to 57 nm thick, a high refractive index layer having a refractive index greater than 1.6 30 to 58nm thick optionally an electrically conductive layer 3 to 1 μm thick, and a low refractive index layer having a refractive index less than 1.55 of 84 to 114 nm thick.
    [0012]
    An ophthalmic lens according to claim 10, any one of the preceding claims, characterized in that the interference coating comprises, in the direction away from the substrate, a layer of high refractive index having a higher refractive index. at 1.6 from 19 to 39 nm thick, a low refractive index layer having a refractive index less than 1.55 from 26 to 46 nm thick, a high refractive index layer having a refractive index greater than 1.6 from 43 to 63nm thick, a low refractive index layer having a refractive index of less than 1.55 from 52 to 72nm thick, a high refractive index layer having a refractive index greater than 1.6 from 24 to 44nrn thick, a low refractive index layer having a refractive index of less than 1.55 from 44 to 64nm thick, a high refractive index layer having a refractive index sup 1.6 to 28 nm thick, optionally an electrically conductive layer 3 to 10 nm thick, and a low refractive index layer having a refractive index of less than 1.55 from 95 to 116 nm. thick.
    [0013]
    An ophthalmic lens according to any one of the preceding claims, wherein the UV reflection factor Ru, on said back main face between 280 nm and 380 nm weighted by the W (X) function is less than or equal to 10 %, preferably less than or equal to 5%, ideally less than or equal to 3%, for an angle of incidence of 350.
    [0014]
    14. Ophthalmic lens according to any one of the preceding claims, wherein the ESPF coefficient of the lens is greater than 10, preferably greater than 15, ideally greater than 20. 3031195 27
    [0015]
    15. A method of manufacturing an ophthalmic lens according to any one of the preceding claims, characterized in that the deposition of the multilayer interference coating is carried out under vacuum.
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    同族专利:
    公开号 | 公开日
    EP3237939B1|2020-03-18|
    CN107111000B|2019-09-17|
    US20170351119A1|2017-12-07|
    CN107111000A|2017-08-29|
    WO2016102857A1|2016-06-30|
    FR3031195B1|2017-02-10|
    EP3237939A1|2017-11-01|
    US10288905B2|2019-05-14|
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    FR2968774B1|2010-12-10|2013-02-08|Essilor Int|OPTICAL ARTICLE COMPRISING A LOW REFLECTIVE ANTIREFLECTION COATING IN THE ULTRAVIOLET DOMAIN AND THE VISIBLE DOMAIN|
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    CN106461965B|2014-05-05|2020-01-07|依视路国际公司|Optical article comprising an antireflection coating having a very low reflection in the visible and ultraviolet range|EP3392680A1|2017-04-18|2018-10-24|Essilor International|Optical article having an abrasion and temperature resistant interferential coating with an optimized thickness ratio of low and high refractive index layers|
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    EP3884314A2|2018-11-19|2021-09-29|Essilor International|Optical lens having a mirror coating and a multilayer system for improving abrasion-resistance|
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    法律状态:
    2015-12-17| PLFP| Fee payment|Year of fee payment: 2 |
    2016-07-01| PLSC| Publication of the preliminary search report|Effective date: 20160701 |
    2016-12-27| PLFP| Fee payment|Year of fee payment: 3 |
    2017-12-27| PLFP| Fee payment|Year of fee payment: 4 |
    2018-07-06| TP| Transmission of property|Owner name: ESSILOR INTERNATIONAL, FR Effective date: 20180601 |
    2019-12-26| PLFP| Fee payment|Year of fee payment: 6 |
    2020-12-27| PLFP| Fee payment|Year of fee payment: 7 |
    2021-12-27| PLFP| Fee payment|Year of fee payment: 8 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1463344A|FR3031195B1|2014-12-24|2014-12-24|OPTICAL ARTICLE COMPRISING AN INTERFERENTIAL COATING WITH HIGH REFLECTION IN THE FIELD OF ULTRAVIOLET|FR1463344A| FR3031195B1|2014-12-24|2014-12-24|OPTICAL ARTICLE COMPRISING AN INTERFERENTIAL COATING WITH HIGH REFLECTION IN THE FIELD OF ULTRAVIOLET|
    CN201580070831.9A| CN107111000B|2014-12-24|2015-12-18|Including the optical article in ultraviolet region interference coatings with high reflectivity|
    US15/539,037| US10288905B2|2014-12-24|2015-12-18|Optical article comprising an interference coating with high reflectivity in the ultraviolet region|
    PCT/FR2015/053656| WO2016102857A1|2014-12-24|2015-12-18|Optical article comprising an interference coating with high reflectivity in the ultraviolet region|
    EP15825617.2A| EP3237939B1|2014-12-24|2015-12-18|Optical article comprising an interference coating with high reflectivity in the ultraviolet region|
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